(2-Amino-4,6-dimethylpyrimidine-κN 1)(2-amino-4-methylpyrimidine-κN 1)silver(I) nitrate
نویسنده
چکیده
Colourless crystals of the title compound, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]NO(3), separated out of a solution of 2-amino-4-methyl-pyrimidine, 2-amino-4,6-dimethyl-pyrimidine and silver nitrate in water and methanol. The central Ag(I) ion is coordinated by two different N atoms in the aromatic rings of the ligands, with an N-Ag-N angle of 173.9 (2)°. The crystal structure is composed of two complexed cations and stabilized by an inter-molecular N-H⋯O and N-H⋯N hydrogen-bond network and there is π-π stacking of the aromatic rings [inter-planar distance 3.651 (10) Å].
منابع مشابه
(2-Amino-4,6-dimethylpyrimidine-κN 1)(2-amino-4-methylpyrimidine-κN 1)silver(I) perchlorate
Colourless crystals of the title mixed ligand complex, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]ClO(4), were obtained from a solution of 2-amino-4-methyl-pyrimidine, 2-amino-4,6-dimethyl-pyrim-idine and silver perchlorate in water and methanol. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds and π-π stacking inter-actions of the aromatic rings of the two ligands [in...
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